boiling point of isopentyl acetate

The sulfuric acid was used as a catalyst in the reaction. Please upgrade your Internet Explorer to a newer version. The major product that was formed from the Fischer Esterification of isopentyl alcohol and acetic acid was isopentyl acetate. It is a colorless liquid that is only slightly soluble in water, but very soluble in most organic solvents. Isopentyl acetate anhydrous, ≥99% Synonym: Acetic acid 3-methylbutyl ester, Isoamyl acetate CAS Number 123-92-2. At the end of the experiment, a successful esterification was performed from the starting acetic acid, using isopentenyl alcohol to make the product of Isopentyl acetate. Molecular Weight 130.18 . Physical and chemical properties Physical State Liquid Appearance Colorless Odor sweet Odor Threshold No information available pH No information available Melting Point/Range-78 °C / -108.4 °F Boiling Point/Range 142 °C / 287.6 … Information on Registered Substances comes from registration dossiers which have been assigned a registration number. MDL number MFCD00008946 MDL number MFCD00008946. Source: Acros Acetic Acid Isopentyl Alcohol Sulfuric Acid Isopentyl Acetate Molecular Weight (g/mol) 60.05 … The reactants were heated using a reflux apparatus so that the product would not be lost, helping serve as a catalyst in the reaction.1 Any remaining water left over from the esterification process was dried using anhydrous sodium sulfate. This site is not fully supported in Internet Explorer 7 (and earlier versions). Molecular Weight 130.18 . PREPARATION OF ISOPENTYL ACETATE (BANANA OIL) Have your lab textbook available for quick reference to specific pages, indicated in red. The percent yield of the isopentyl acetate was 61.9 % (as seen in table 1) with a theoretical yield of 6.44g. We’ll occasionally send you promo and account related emails. Procedure and Observations: A mixture of 5.0mL (4.111g) of isopentyl alcohol, 7.0mL of glacial acetic acid, and 1mL of concentrated sulfuric acid was added to a 25mL round-bottomed flask.  The round-bottomed flask was hooked to the reflux apparatus and the mixture was brought to a boil for an hour. PubChem Substance ID 57648464. NACRES NA.21 The above also means that the boiling point of a substance under vacuum is lower than the boiling point of the same substance in an open system. Isoamyl acetate has a strong odor which is described as similar to both banana and pear. The peak at 1231 indicates methyl group. Close Find out more on how we use cookies. This is because the ester formed is the equatorial position, which makes the compound more stable than cis-4-tert-butylcyclohexanol. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). Web. It is one of several isomers of amyl alcohol (pentanol). After the boiling point range has been obtained the flask was left to cool down, weighed and then an IR and NMR samples were submitted for identification. All rights reserved. Based on the experiment that was conducted the synthesis of isopentyl acetate from a carboxylic acid and an alcohol could be done by a Fisher Esterification reaction, and the percent yield of the product is about 61.9%. Linear Formula CH 3 COOCH 2 CH 2 CH(CH 3) 2. “Alcohol Reactivity.” Alcohol Reactivity. A gas chromatograph is used to assess the purity of the product. Acetic acid, octyl ester The study is not performed according to an acknowledged standard method. Isoamyl alcohol is a colorless liquid with the formula C 5 H 12 O, specifically (H 3 C–) 2 CH–CH 2 –CH 2 –OH. In both animals increased tear fluid and saliva generation. Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice. The peak at 1056 indicates residual acetic acid (R-Cl), which can be seen on Appendix D-G. Particle size distribution (Granulometry), Solubility in organic solvents / fat solubility, Stability in organic solvents and identity of relevant degradation products, Storage stability and reactivity towards container material, Biodegradation in water and sediment: simulation tests, Additional information on environmental fate and behaviour, Short-term toxicity to aquatic invertebrates, Long-term toxicity to aquatic invertebrates, Toxicity to aquatic algae and cyanobacteria, Toxicity to aquatic plants other than algae, Endocrine disrupter testing in aquatic vertebrates – in vivo, Toxicity to soil macroorganisms except arthropods, Endocrine disrupter mammalian screening – in vivo (level 3), Direct observations: clinical cases, poisoning incidents and other, Exposure related observations in humans: other data, Trial Nr. Isopentyl acetate Synonym: Acetic acid 3-methylbutyl ester, Isoamyl acetate CAS Number 123-92-2. Introduction Esters are a class of compounds found widely in nature. “Experiment 4 Background.” Experiment 4 Background. Welcome to the ECHA website. Beilstein/REAXYS Number 1744750 . Accessed:17 Feb. 2017. After the boiling point range has been obtained the flask was left to cool down, weighed and then an IR and NMR samples were submitted for identification. An obsolete name for it was isobutyl carbinol. The irritation eases with each daily exposure. 142 °C Alfa Aesar: 288 F (142.2222 °C) NIOSH NS9800000 145 °C Food and Agriculture Organization of the United Nations 3-Methylbutyl acetate: 143 °C OU Chemical Safety Data (No longer updated) More details: 142 °C Alfa Aesar B21618: 142 °C (Literature) LabNetwork LN00163295 142 °C FooDB FDB008132: 287-289 F / 760 mmHg (141.6667-142.7778 °C / 760 mmHg) Wikidata Q221307 For the IR spectrum data, the -C-CO 2R stretch characteristic of an ester is visible in the pure isopentyl acetate IR spectrum in the 1735-1745 cm -1 range. The peak at 1747 indicates the aldehyde (C=O). Typically, only primary and secondary alcohols are used in the Fisher method since tertiary alcohols are prone to elimination.3 In this lab, a Fisher Esterification was performed to synthesize isopentyl acetate from isopentyl alcohol and acetic acid as seen in figure 1. Esters are prepared in many ways and one of which is through Fischer Esterification. MDL number MFCD00008946. The excess acetic acid was used in order for the reaction to favor esterification. This website uses cookies to ensure you get the best experience on our websites. Pure isoamyl acetate, or mixtures of isoamyl acetate, amyl acetate, and other flavors may be referred to as Banana oil. Isoamyl acetate: CAS Number: 123-92-2: Molecular Weight: 130.185: Density: 0.9±0.1 g/cm3: Boiling Point: 142.1±0.0 °C at 760 mmHg: Molecular Formula: C 7 H 14 O 2: Melting Point-78 °C: MSDS: Chinese USA: Flash Point: 25.0±0.0 °C: Symbol: GHS02: Signal Word: Warning × Acetic acid octyl ester. In the sediment, Additional physico-chemical properties of nanomaterials, Toxicokinetics, metabolism and distribution. Octyl acetate. 1. The normal boiling point is defined for an external pressure of 1 atm, or 760 mm Hg. Isopentyl Acetate (Banana oil) Dean Antic, Ph.D., Thermo Fisher Scientific, Boulder, CO, USA . Source: Acros Acetic Acid Isopentyl Alcohol Sulfuric Acid Isopentyl Acetate Molecular Weight (g/mol) 60.05 … Effect of Gold Nanoparticles on Bilharziasis, The Chemistry Of Fireworks Chemistry Essay, http://www.reed.edu/chemistry/alan/201_202/lab_manual/Expt_banana_oil/background.html, http://pubs.acs.org/doi/abs/10.1021/je00037a019, https://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/alcohol1.htm, CustomWritings – Professional Academic Writing Service, Tips on How to Order Essay. The mixture was cooled to room temperature, placed into an ice bath, and put in a separatory funnel with 10mL of water.  The funnel was shaken vigorously and vented several times.  The bottom layer was drained from the separatory funnel into a beaker.  5mL of 5% sodium bicarbonate was then put into the separatory funnel.  The separatory funnel was shaken and vented several times.  The bottom layer was drained into the same beaker.  5mL of saturated sodium chloride was added to the contents of the separatory funnel.  The separatory funnel was shaken and vented several times.  The bottom layer was drained into a different beaker.  The mixture that was left in the separatory funnel was transferred to an Erlenmeyer flask with 1g of anhydrous sodium sulfate.  The flask was corked and was left to sit for 10 to 15 minutes.  The mixture was transferred to another Erlenmeyer flask and .503g of anhydrous sodium sulfate was added.  A distillation apparatus was assembled with the receiving flask immersed in an ice bath.  The mixture was transferred into a round-bottomed flask and attached to the distillation apparatus.  The product that was now in the receiving flask was then weighed.  The percent yield was determined and an IR was done on the product.

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